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Issue 13, 2006
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Cationic phosphorus–carbon–pnictogen cages isolobal to [C5R5]+

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Abstract

The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

Graphical abstract: Cationic phosphorus–carbon–pnictogen cages isolobal to [C5R5]+

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Publication details

The article was received on 14 Dec 2005, accepted on 02 Feb 2006 and first published on 17 Feb 2006


Article type: Communication
DOI: 10.1039/B517710C
Citation: Chem. Commun., 2006,0, 1375-1377
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    Cationic phosphorus–carbon–pnictogen cages isolobal to [C5R5]+

    C. Fish, M. Green, J. C. Jeffery, R. J. Kilby, J. M. Lynam, J. E. McGrady, D. A. Pantazis, C. A. Russell and C. E. Willans, Chem. Commun., 2006, 0, 1375
    DOI: 10.1039/B517710C

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