Two hydrogen-bonds from geometrically constrained OH groups to coordinated oxygen donors shift the reduction potential of a CuII complex by +270 mV as compared to the structurally analogous reference complex missing the OH groups.
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Direct influence of hydrogen-bonding on the reduction potential of a CuII center
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a
Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie, Universität Bielefeld, Universitätsstr. 25, Germany
E-mail: thorsten.glaser@uni-bielefeld.de ;
Fax: (+49) 521-106-6003
E-mail: thorsten.glaser@uni-bielefeld.de ;
Fax: (+49) 521-106-6003
b
Organisch-Chemisches Institut, Corrensstr. 40, Westfälische Wilhelms-Universität Münster, Germany
Chem. Commun., 2006, 1024-1026
DOI: 10.1039/B517340J
Received 08 Dec 2005, Accepted 04 Jan 2006
First published online 23 Jan 2006
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