Issue 9, 2006
From the journal:

Chemical Communications

A deuterated deep-cavity cavitand confirms the importance of C–H⋯X–R hydrogen bonds in guest binding†

Zachary R. Laughrey,a   Thomas G. Upton‡a  and  Bruce C. Gibb*a  

* Corresponding authors

a Department of Chemistry, University of New Orleans, New Orleans, USA
E-mail: bgibb@uno.edu
Fax: +1-504-280-6860
Tel: +1-504-280-3152

Abstract

A deuterated cavitand host was examined for its affinity to a series of guests; for halogenated, preorganized guests binding was significantly stronger than the corresponding protium host.

Graphical abstract: A deuterated deep-cavity cavitand confirms the importance of C–H⋯X–R hydrogen bonds in guest binding

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Article information

DOI
https://doi.org/10.1039/B515187B
Article type
Communication
Submitted
25 Oct 2005
Accepted
22 Dec 2005
First published
20 Jan 2006

Chem. Commun., 2006, 970-972

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A deuterated deep-cavity cavitand confirms the importance of C–H⋯X–R hydrogen bonds in guest binding

Z. R. Laughrey, T. G. Upton and B. C. Gibb, Chem. Commun., 2006, 970 DOI: 10.1039/B515187B

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