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Issue 7, 2006
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One step assembly of a nonanuclear CrIII2NiII7 bimetallic cyanide bridged complex

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Abstract

The reaction of hexacyanochromate with connectivity 6 and a mononuclear Ni complex bearing a bulky tridentate macrocycle leads in one step to the formation of a nonanuclear Cr2Ni7 complex with central low spin and peripheral high spin Ni ions; fast tunnelling of the magnetization is observed at low temperature by micro-SQUID studies on a single crystal.

Graphical abstract: One step assembly of a nonanuclear Criii2Niii7 bimetallic cyanide bridged complex

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Publication details

The article was received on 04 Oct 2005, accepted on 17 Nov 2005 and first published on 04 Jan 2006


Article type: Communication
DOI: 10.1039/B514053F
Citation: Chem. Commun., 2006,0, 735-737
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    One step assembly of a nonanuclear CrIII2NiII7 bimetallic cyanide bridged complex

    J. Rebilly, L. Catala, E. Rivière, R. Guillot, W. Wernsdorfer and T. Mallah, Chem. Commun., 2006, 0, 735
    DOI: 10.1039/B514053F

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