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Issue 39, 2006
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Efficient stabilization of copper(III) in tetraaza pseudo-macrocyclic oxime-and-hydrazide ligands with adjustable cavity size

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Abstract

Substitution of the amide donors in open-chain {2N(oxime), 2N(amide)} ligands by hydrazide donors gives new pseudo-macrocyclic copper complexes that show a significant decrease of the Cu3+/2+ redox potentials in both mono- and polynuclear systems, thus demonstrating a pronounced capacity of such ligand systems to efficiently stabilize the trivalent copper.

Graphical abstract: Efficient stabilization of copper(iii) in tetraaza pseudo-macrocyclic oxime-and-hydrazide ligands with adjustable cavity size

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Publication details

The article was received on 09 Jun 2006, accepted on 26 Jul 2006 and first published on 22 Aug 2006


Article type: Communication
DOI: 10.1039/B608236J
Citation: Chem. Commun., 2006,0, 4125-4127
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    Efficient stabilization of copper(III) in tetraaza pseudo-macrocyclic oxime-and-hydrazide ligands with adjustable cavity size

    I. O. Fritsky, H. Kozłowski, O. M. Kanderal, M. Haukka, J. Świątek-Kozłowska, E. Gumienna-Kontecka and F. Meyer, Chem. Commun., 2006, 0, 4125
    DOI: 10.1039/B608236J

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