Issue 30, 2006
From the journal:

Chemical Communications

Accessing tetrahydrofuran-based natural products by microbial Baeyer–Villiger biooxidation†

Marko D. Mihovilovic,*a   Dario A. Bianchi‡a  and  Florian Rudroff‡a  

* Corresponding authors

a Vienna University of Technology, Institute of Applied Synthetic Chemistry, Getreidemarkt 9/163-OC, Austria
E-mail: mmihovil@pop.tuwien.ac.at
Fax: +43 1 58801 15499
Tel: +43 1 58801 15420

Abstract

A heterobicyclic lactone obtained by stereoselective Baeyer–Villiger biooxidation with recombinant whole-cells expressing cyclopentanone monooxygenase from Comamonas sp. NCIMB 9872 was used for formal total syntheses of various natural products containing a tetrahydrofuran structural motif.

Graphical abstract: Accessing tetrahydrofuran-based natural products by microbial Baeyer–Villiger biooxidation

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Article information

DOI
https://doi.org/10.1039/B606633J
Article type
Communication
Submitted
10 May 2006
Accepted
30 May 2006
First published
19 Jun 2006

Chem. Commun., 2006, 3214-3216

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Accessing tetrahydrofuran-based natural products by microbial Baeyer–Villiger biooxidation

M. D. Mihovilovic, D. A. Bianchi and F. Rudroff, Chem. Commun., 2006, 3214 DOI: 10.1039/B606633J

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