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Issue 34, 2006
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Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes

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Abstract

Isotopic desymmetrisation, as well as (stereo)chemical correlation, has illuminated significant aspects of the σ–π–σ mechanism of copper-catalysed allylic substitution reactions: an enantiospecific and regioselective access to α-chiral silanes is presented.

Graphical abstract: Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes

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Publication details

The article was received on 09 May 2006, accepted on 04 Jul 2006 and first published on 28 Jul 2006


Article type: Communication
DOI: 10.1039/B606589A
Citation: Chem. Commun., 2006, 3643-3645
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    Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes

    E. S. Schmidtmann and M. Oestreich, Chem. Commun., 2006, 3643
    DOI: 10.1039/B606589A

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