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Issue 30, 2006
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The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings

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Abstract

The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C–F⋯N+ interaction.

Graphical abstract: The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings

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Publication details

The article was received on 04 May 2006, accepted on 26 May 2006 and first published on 21 Jun 2006


Article type: Communication
DOI: 10.1039/B606334A
Citation: Chem. Commun., 2006,0, 3190-3192
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    The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings

    N. E. J. Gooseman, D. O'Hagan, A. M. Z. Slawin, A. M. Teale, D. J. Tozer and R. J. Young, Chem. Commun., 2006, 0, 3190
    DOI: 10.1039/B606334A

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