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Issue 31, 2006
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Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon–carbon coupling reactions under room-temperature

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Abstract

A new bisphosphine ligand, C8-BINAP, and C8-BINAP-stabilized palladium nanoparticles have been prepared; C8-BINAP was found to be an effective protecting ligand for preparing and stabilizing palladium nanoparticles with very small core size and narrow size distribution and the C8-BINAP–Pd nanoparticles behave as an efficient catalyst for carbon–carbon coupling reactions at room temperature.

Graphical abstract: Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon–carbon coupling reactions under room-temperature

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Publication details

The article was received on 13 Apr 2006, accepted on 05 Jun 2006 and first published on 23 Jun 2006


Article type: Communication
DOI: 10.1039/B605390B
Citation: Chem. Commun., 2006,0, 3349-3351
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    Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon–carbon coupling reactions under room-temperature

    R. Tatumi, T. Akita and H. Fujihara, Chem. Commun., 2006, 0, 3349
    DOI: 10.1039/B605390B

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