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Issue 28, 2006
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Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

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Abstract

The bonding in Mn(η2-SiH) complexes is interpreted in terms of an asymmetric oxidative addition whose extent is controlled by the substitution pattern at the hypercoordinate silicon centre, and especially by the ligand trans to the η2-coordinating SiH moiety.

Graphical abstract: Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

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Publication details

The article was received on 12 Apr 2006, accepted on 17 May 2006 and first published on 07 Jun 2006


Article type: Communication
DOI: 10.1039/B604843A
Citation: Chem. Commun., 2006,0, 2986-2988
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    Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

    W. Scherer, G. Eickerling, M. Tafipolsky, G. S. McGrady, P. Sirsch and N. P. Chatterton, Chem. Commun., 2006, 0, 2986
    DOI: 10.1039/B604843A

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