A new Co(II) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC				≈ 68 K

Simon M. Humphrey; Antonio Alberola; Carlos J. Gómez García; Paul T. Wood

doi:10.1039/B600347H

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A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with T_C ≈ 68 K

Simon M. Humphrey,†^a Antonio Alberola,^a Carlos J. Gómez García^b and Paul T. Wood*^a

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* Corresponding authors

^a University Chemical Laboratory, Lensfield Rd, Cambridge, UK
E-mail: ptw22@cam.ac.uk
Fax: +44 1223 336017

^b Instituto de Ciencia Molecular, Universidad de Valencia. Pol. La Coma s/n, 46980 Paterna, Valencia, Spain

Abstract

Reaction of Co(II) chloride with the sodium salt of 2-mercaptonicotinic acid in water at 200 °C results in the formation of Co₄(2-mna)₄(H₂O), which orders as a canted antiferromagnet at 68 K.

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Supplementary files

Crystal structure data TXT (21K)

Article information

DOI: https://doi.org/10.1039/B600347H
Article type: Communication
Submitted: 13 Jan 2006
Accepted: 23 Feb 2006
First published: 08 Mar 2006

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Chem. Commun., 2006, 1607-1609

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A new Co(II) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with T_C ≈ 68 K

S. M. Humphrey, A. Alberola, C. J. G. García and P. T. Wood, Chem. Commun., 2006, 1607 DOI: 10.1039/B600347H

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