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Issue 27, 2006
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Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

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Abstract

The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic–inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.

Graphical abstract: Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

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Publication details

The article was received on 06 Jan 2006, accepted on 26 May 2006 and first published on 08 Jun 2006


Article type: Communication
DOI: 10.1039/B600159A
Citation: Chem. Commun., 2006, 2878-2880
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    Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

    A. Ranganathan, A. El-Ghayoury, C. Mézière, E. Harté, R. Clérac and P. Batail, Chem. Commun., 2006, 2878
    DOI: 10.1039/B600159A

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