Issue 3, 2006
From the journal:

Chemical Communications

Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer†

Emma Denehy,ab   Jonathan M. Whiteab  and  Spencer J. Williams*ab  

* Corresponding authors

a School of Chemistry, University of Melbourne, Parkville, Australia

b Bio21 Biotechnology and Molecular Science Institute, University of Melbourne, Parkville, Australia
E-mail: sjwill@unimelb.edu.au
Fax: +61 3 9347 8124
Tel: 61 3 8344 2422

Abstract

Structure/reactivity and structure/structure correlations of 5 sulfate monoesters and 11 sulfamate esters determined by low temperature X-ray crystallography reveal similar ground state deformations that suggest similar reaction coordinates for sulfuryl and sulfamyl group transfer.

Graphical abstract: Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer

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Article information

DOI
https://doi.org/10.1039/B513712H
Article type
Communication
Submitted
28 Sep 2005
Accepted
04 Nov 2005
First published
21 Nov 2005

Chem. Commun., 2006, 314-316

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Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer

E. Denehy, J. M. White and S. J. Williams, Chem. Commun., 2006, 314 DOI: 10.1039/B513712H

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