Issue 1, 2006
From the journal:

Chemical Communications

A steep one-step [HS–HS] to [LS–LS] spin transition in a 4,4′-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(ii) dimer†

Ko Yoneda,a   Keiichi Adachi,a   Shinya Hayami,b   Yonezo Maeda,b   Motomi Katada,c   Akira Fuyuhiro,a   Satoshi Kawata*a  and  Sumio Kaizaki*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan
E-mail: kawata@chem.sci.osaka-u.ac.jp; kaizaki@chem.sci.osaka-u.ac.jp
Fax: +81-6-6850-5473

b Department of Chemistry, Graduate School of Science, Kyushu University, Fukuoka, Japan

c Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachiouji, Japan

Abstract

The variable temperature magnetic susceptibility, X-ray crystallography, and Mössbauer and Raman spectra of a new dinuclear complex-based one-dimensional coordination polymer [{FeII2(NCS)2(μ-bpypz)2}(μ-4,4′-bpy)]·MeOH demonstrated a steep one-step [HS–HS] to [LS–LS] spin transition.

Graphical abstract: A steep one-step [HS–HS] to [LS–LS] spin transition in a 4,4′-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(ii) dimer

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Article information

DOI
https://doi.org/10.1039/B512266J
Article type
Communication
Submitted
31 Aug 2005
Accepted
06 Oct 2005
First published
20 Oct 2005

Chem. Commun., 2006, 45-47

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A steep one-step [HS–HS] to [LS–LS] spin transition in a 4,4′-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer

K. Yoneda, K. Adachi, S. Hayami, Y. Maeda, M. Katada, A. Fuyuhiro, S. Kawata and S. Kaizaki, Chem. Commun., 2006, 45 DOI: 10.1039/B512266J

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