A straightforward approach towards thiazoles and endothiopeptides via Ugi reaction

Uli Kazmaier; Stefanie Ackermann

doi:10.1039/B507028G

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Organic & Biomolecular Chemistry

Issue 17, 2005

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A straightforward approach towards thiazoles and endothiopeptides via Ugi reaction

Uli Kazmaier and Stefanie Ackermann

Org. Biomol. Chem., 2005, 3, 3184-3187

DOI: 10.1039/B507028G
Received 18 May 2005, Accepted 29 Jun 2005
First published on the web 26 Jul 2005

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Abstract
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Endothiopeptides can easily be obtained via Ugi reaction using thio acids as acid components. If isonitriles with an acetal group are applied, the endothiopeptides can directly be converted into thiazoles using TMSCl–NaI under microwave irradiation.

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preparation and analytical/spectroscopic data of all peptides 2 and 3 as well as the thiazoles 6
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Organic & Biomolecular Chemistry

A straightforward approach towards thiazoles and endothiopeptides via Ugi reaction

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