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Issue 6, 2005
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Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

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Abstract

We report the development of a new class of readily prepared chiral 4-(pyrrolidino)-pyridine catalysts capable of exploiting both van der Waals (π) and H-bonding interactions, thus allowing remote chiral information to stereochemically control the kinetic resolution of sec-alcohols.

Graphical abstract: Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

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Publication details

The article was received on 04 Jan 2005, accepted on 25 Jan 2005 and first published on 10 Feb 2005


Article type: Communication
DOI: 10.1039/B419335K
Citation: Org. Biomol. Chem., 2005,3, 981-984
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    Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

    C. Ó. Dálaigh, S. J. Hynes, D. J. Maher and S. J. Connon, Org. Biomol. Chem., 2005, 3, 981
    DOI: 10.1039/B419335K

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