Issue 6, 2005
From the journal:

Organic & Biomolecular Chemistry

Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

Ciarán Ó Dálaigh,a   Stephen J. Hynes,a   Declan J. Mahera  and  Stephen J. Connon*a  

* Corresponding authors

a Department of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland
E-mail: connons@tcd.ie
Fax: +353 1 6712826

Abstract

We report the development of a new class of readily prepared chiral 4-(pyrrolidino)-pyridine catalysts capable of exploiting both van der Waals (π) and H-bonding interactions, thus allowing remote chiral information to stereochemically control the kinetic resolution of sec-alcohols.

Graphical abstract: Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

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Article information

DOI
https://doi.org/10.1039/B419335K
Article type
Communication
Submitted
04 Jan 2005
Accepted
25 Jan 2005
First published
10 Feb 2005

Org. Biomol. Chem., 2005,3, 981-984

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Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

C. Ó. Dálaigh, S. J. Hynes, D. J. Maher and S. J. Connon, Org. Biomol. Chem., 2005, 3, 981 DOI: 10.1039/B419335K

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