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Issue 8, 2005
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A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

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Abstract

A transition-state analogue (TSA) for an acetal hydrolysis reaction was found to select and amplify a macrocycle from a dynamic combinatorial library (DCL) of disulfides in water. This host was able to accelerate the reaction by a factor of two; a similar value was progressively reached when the macrocycle was gradually produced in the course of the reaction.

Graphical abstract: A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

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Publication details

The article was received on 15 Apr 2005, accepted on 16 Jun 2005 and first published on 01 Jul 2005


Article type: Letter
DOI: 10.1039/B505316A
Citation: New J. Chem., 2005,29, 1001-1003
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    A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

    L. Vial, J. K. M. Sanders and S. Otto, New J. Chem., 2005, 29, 1001
    DOI: 10.1039/B505316A

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