Issue 22, 2005
From the journal:

Dalton Transactions

Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(ii) and manganese(ii)†

Cynthia Brewer,a   Greg Brewer,*a   Ray J. Butcher,b   Everett E. Carpenter,c   Luciann Cuenca,a   Ann M. Schmiedekampd  and  Carol Viragha  

* Corresponding authors

a The Catholic University of America, Washington, USA
E-mail: brewer@cua.edu

b Department of Chemistry, Howard University, Washington, USA

c Department of Chemistry, Virginia Commonwealth University, Richmond, VA USA, USA

d Penn. State University, Abington College, Abington, PA, USA

Abstract

The iron(II) and manganese(II) complexes of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, ∼2.44 Å, metal to apical nitrogen bond.

Graphical abstract: Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(ii) and manganese(ii)

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Article information

DOI
https://doi.org/10.1039/B511566C
Article type
Communication
Submitted
15 Aug 2005
Accepted
19 Sep 2005
First published
03 Oct 2005

Dalton Trans., 2005, 3617-3619

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Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

C. Brewer, G. Brewer, R. J. Butcher, E. E. Carpenter, L. Cuenca, A. M. Schmiedekamp and C. Viragh, Dalton Trans., 2005, 3617 DOI: 10.1039/B511566C

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