Manganese(I) poly(mercaptoimidazolyl)borate complexes: spectroscopic and structural characterization of MnH–B interactions in solution and in the solid state

Leigh A. Graham; Alison R. Fout; Karl R. Kuehne; Jennifer L. White; Bhaskar Mookherji; Fred M. Marks; Glenn P. A. Yap; Lev N. Zakharov; Arnold L. Rheingold; Daniel Rabinovich

doi:10.1039/B412280A

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Dalton Transactions

Issue 1, 2005

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Manganese(I) poly(mercaptoimidazolyl)borate complexes: spectroscopic and structural characterization of MnH–B interactions in solution and in the solid state

Leigh A. Graham , Alison R. Fout , Karl R. Kuehne , Jennifer L. White , Bhaskar Mookherji , Fred M. Marks , Glenn P. A. Yap , Lev N. Zakharov , Arnold L. Rheingold and Daniel Rabinovich

Dalton Trans., 2005, 171-180

DOI: 10.1039/B412280A
Received 09 Aug 2004, Accepted 01 Nov 2004
First published on the web 23 Nov 2004

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The manganese(I) tricarbonyl complexes (Bm^R)Mn(CO)₃ (R = Me, Bz, Bu^t, p-Tol) and (PhBm^Me)Mn(CO)₃, the first bis(mercaptoimidazolyl)borate derivatives for this metal, have been readily prepared and fully characterized. In particular, the presence of three-center–two-electron MnH–B interactions in these species, both in solution and in the solid state, has been investigated using a combination of IR and NMR spectroscopies and, in the case of the methyl-, tert-butyl- and para-tolyl-substituted derivatives, by X-ray crystallography. To complement these synthetic and structural studies, the tris(mercaptoimidazolyl)borate complexes (Tm^Me)Mn(CO)₃ (R = Me, Bz, Bu^t, p-Tol) and (PhTm^Me)Mn(CO)₃, as well as the related pyrazolylbis(mercaptoimidazolyl)borate (pzBm^Me)Mn(CO)₃, have also been synthesized and characterized by a combination of analytical and spectroscopic techniques.

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Manganese(I) poly(mercaptoimidazolyl)borate complexes: spectroscopic and structural characterization of MnH–B interactions in solution and in the solid state

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