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Issue 4, 2005
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Ionic radii for Group 1 halide crystals and ion-pairs

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Abstract

Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion-pairs appear to be anomalous. Soft-sphere ionic radii are compared with atomic radii of noble gases.

Graphical abstract: Ionic radii for Group 1 halide crystals and ion-pairs

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Publication details

The article was received on 09 Jul 2004, accepted on 22 Dec 2004 and first published on 17 Jan 2005


Article type: Paper
DOI: 10.1039/B410521B
Citation: Dalton Trans., 2005,0, 702-705
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    Ionic radii for Group 1 halide crystals and ion-pairs

    R. J. Collin and B. C. Smith, Dalton Trans., 2005, 0, 702
    DOI: 10.1039/B410521B

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