Elucidating excited state electronic structure and intercomponent interactions in multicomponent and supramolecular systems

Wesley R. Browne; Noel M. O'Boyle; John J. McGarvey; Johannes G. Vos

doi:10.1039/B400513A

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Chemical Society Reviews

Issue 8, 2005

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Elucidating excited state electronic structure and intercomponent interactions in multicomponent and supramolecular systems

Wesley R. Browne , Noel M. O'Boyle , John J. McGarvey and Johannes G. Vos

Chem. Soc. Rev., 2005, 34, 641-663

DOI: 10.1039/B400513A
Received 30 Apr 2005, First published on the web 24 Jun 2005

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Rational design of supramolecular systems for application in photonic devices requires a clear understanding of both the mechanism of energy and electron transfer processes and how these processes can be manipulated. Central to achieving these goals is a detailed picture of their electronic structure and of the interaction between the constituent components. We review several approaches that have been taken towards gaining such understanding, with particular focus on the physical techniques employed. In the discussion, case studies are introduced to illustrate the key issues under consideration.

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Elucidating excited state electronic structure and intercomponent interactions in multicomponent and supramolecular systems

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