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Issue 47, 2005
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Generation and ring opening of aziridine N-carbonyl radicals

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Abstract

Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin.

Graphical abstract: Generation and ring opening of aziridine N-carbonyl radicals

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Publication details

The article was received on 13 Sep 2005, accepted on 06 Oct 2005 and first published on 03 Nov 2005


Article type: Communication
DOI: 10.1039/B512956G
Citation: Chem. Commun., 2005,0, 5928-5930
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    Generation and ring opening of aziridine N-carbonyl radicals

    M. R. Heinrich, I. Pérez-Martín and S. Z. Zard, Chem. Commun., 2005, 0, 5928
    DOI: 10.1039/B512956G

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