Issue 47, 2005
From the journal:

Chemical Communications

Generation and ring opening of aziridineN-carbonyl radicals

Markus R. Heinrich,ab   Inés Pérez-Martína  and  Samir Z. Zard*a  

* Corresponding authors

a Organische Chemie 1, Technische Universität München, Lichtenbergstr. 4, Germany
E-mail: Markus.Heinrich@ch.tum.de

b Laboratoire de Synthèse Organique associé au C.N.R.S., Ecole Polytechnique, France
E-mail: zard@poly.polytechnique.fr
Fax: +33 169333851
Tel: +33 169334872

Abstract

Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin.

Graphical abstract: Generation and ring opening of aziridine N-carbonyl radicals

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Article information

DOI
https://doi.org/10.1039/B512956G
Article type
Communication
Submitted
13 Sep 2005
Accepted
06 Oct 2005
First published
03 Nov 2005

Chem. Commun., 2005, 5928-5930

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Generation and ring opening of aziridine N-carbonyl radicals

M. R. Heinrich, I. Pérez-Martín and S. Z. Zard, Chem. Commun., 2005, 5928 DOI: 10.1039/B512956G

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