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Issue 48, 2005
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Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling

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Abstract

Ruthenium trihydrides containing N-heterocyclic carbene ligands display large quantum mechanical exchange couplings in their 1H NMR spectra: DFT calculations are used to explore this phenomenon and to compare them to their phosphine congeners.

Graphical abstract: Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling

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Publication details

The article was received on 08 Sep 2005, accepted on 17 Oct 2005 and first published on 04 Nov 2005


Article type: Communication
DOI: 10.1039/B512760B
Citation: Chem. Commun., 2005,0, 5994-5996
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    Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling

    A. L. Jones, G. S. McGrady, P. Sirsch and J. W. Steed, Chem. Commun., 2005, 0, 5994
    DOI: 10.1039/B512760B

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