Issue 45, 2005
From the journal:

Chemical Communications

A metal–oxo mediated approach to the synthesis of 21,22-diepi-membrarollin†

Yulai Hu‡a  and  Richard C. D. Brown*a  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: rcb1@soton.ac.uk
Fax: 23 8059 4108
Tel: 23 8059 6805

Abstract

A synthesis of 21,22-diepi-membrarollin (14) is described, which employed sequential metal–oxo mediated oxidative cyclisations to introduce six of the seven stereogenic centres.

Graphical abstract: A metal–oxo mediated approach to the synthesis of 21,22-diepi-membrarollin

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Article information

DOI
https://doi.org/10.1039/B512126D
Article type
Communication
Submitted
26 Aug 2005
Accepted
11 Oct 2005
First published
21 Oct 2005

Chem. Commun., 2005, 5636-5637

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A metal–oxo mediated approach to the synthesis of 21,22-diepi-membrarollin

Y. Hu and R. C. D. Brown, Chem. Commun., 2005, 5636 DOI: 10.1039/B512126D

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