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Issue 43, 2005
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The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

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Abstract

The molecular second-order nonlinear optical properties of planar (E)-4-[2-(4-(N-methyl-N-hexadecylaminophenyl)ethenyl]pyridine (L1) and [cis-Ir(CO)2ClL1] and of the significantly twisted new chromophores (E)-4-[(5,6,7,8-tetrahydro-5-isoquinolylidene)methyl]-N-methyl-N-hexadecylaniline (L2) and [cis-Ir(CO)2ClL2] are reported, evidencing for the first time that planarity of a conventional (donor)(π-bridge)(acceptor) structure is not compulsory to reach a large NLO response.

Graphical abstract: The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

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Publication details

The article was received on 30 Jun 2005, accepted on 02 Sep 2005 and first published on 04 Oct 2005


Article type: Communication
DOI: 10.1039/B509258B
Citation: Chem. Commun., 2005,0, 5405-5407
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    The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

    D. Locatelli, S. Quici, D. Roberto and F. De Angelis, Chem. Commun., 2005, 0, 5405
    DOI: 10.1039/B509258B

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