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Issue 37, 2005
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Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

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Abstract

The sterically protected dithiadiazolyl radical (F3C)3C6H2CNSSN˙ (1) crystallises in two polymorphs: , comprised of monomeric units and , containing a mixture of both π*–π* dimers and S = ½ monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.

Graphical abstract: Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

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Publication details

The article was received on 14 Jun 2005, accepted on 01 Aug 2005 and first published on 25 Aug 2005


Article type: Communication
DOI: 10.1039/B508371K
Citation: Chem. Commun., 2005, 4726-4728
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    Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

    A. Alberola, C. S. Clarke, D. A. Haynes, S. I. Pascu and J. M. Rawson, Chem. Commun., 2005, 4726
    DOI: 10.1039/B508371K

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