Anodic aluminium oxide catalytic membranes for asymmetric epoxidation

So-Hye Cho; Nolan D. Walther; SonBinh T. Nguyen; Joseph T. Hupp

doi:10.1039/B507541F

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Chemical Communications

Issue 42, 2005

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Anodic aluminium oxide catalytic membranes for asymmetric epoxidation

So-Hye Cho , Nolan D. Walther , SonBinh T. Nguyen and Joseph T. Hupp

Chem. Commun., 2005, 5331-5333

DOI: 10.1039/B507541F
Received 27 May 2005, Accepted 30 Aug 2005
First published on the web 26 Sep 2005

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Abstract
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Catechol-functionalized (salen)Mn complexes can be supported on mesoporous anodized aluminium oxide disks to yield catalytic membranes that are highly active in the enantioselective epoxidation of olefins when being deployed in a forced-through-flow reactor.

Supplementary Info

Synthetic procedures and characterization data for complexes 1-2; characterization data for 1-AAO; general procedure for asymmetric epoxidations catalyzed by 1-AAO.
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Chemical Communications

Anodic aluminium oxide catalytic membranes for asymmetric epoxidation

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