Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core

Tetsuaki Fujihara; Yasushi Obora; Makoto Tokunaga; Hiromichi Sato; Yasushi Tsuji

doi:10.1039/B506927K

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Chemical Communications

Issue 36, 2005

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Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core

Tetsuaki Fujihara , Yasushi Obora , Makoto Tokunaga , Hiromichi Sato and Yasushi Tsuji

Chem. Commun., 2005, 4526-4528

DOI: 10.1039/B506927K
Received 17 May 2005, Accepted 27 Jul 2005
First published on the web 19 Aug 2005

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Abstract
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Novel dendrimer N-heterocyclic carbene complexes with rhodium(I) located at the core were synthesized, and a positive dendrimer effect was found in the hydrosilylation of ketones catalyzed by them.

Supplementary Info

Synthetic methods and analytical data for 1b-1d and 2b-2d
PDF (227K)
Crystal structure data for 2b.CH ₂Cl ₂
TXT (41K)

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Tetsuaki Fujihara
Yasushi Obora
Makoto Tokunaga
Hiromichi Sato
Yasushi Tsuji

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Chemical Communications

Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core

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