Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

Gavin D. Jones; Chris McFarland; Thomas J. Anderson; David A. Vicic

doi:10.1039/B504996B

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Chemical Communications

Issue 33, 2005

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Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

Gavin D. Jones , Chris McFarland , Thomas J. Anderson and David A. Vicic

Chem. Commun., 2005, 4211-4213

DOI: 10.1039/B504996B
Received 08 Apr 2005, Accepted 24 Jun 2005
First published on the web 22 Jul 2005

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The use of tpy′ (tpy′ = 4,4′,4″-tri-tert-butyl-terpyridine) as a ligand for nickel allows for the isolation of a Ni(I)–alkyl complex and a Ni(II)–alkyl halide complex, both of which can be used as mechanistic probes of key steps in alkyl cross-coupling reactions.

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Chemical Communications

Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

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