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Issue 33, 2005
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Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

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Abstract

The use of tpy′ (tpy′ = 4,4′,4″-tri-tert-butyl-terpyridine) as a ligand for nickel allows for the isolation of a Ni(I)–alkyl complex and a Ni(II)–alkyl halide complex, both of which can be used as mechanistic probes of key steps in alkyl cross-coupling reactions.

Graphical abstract: Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

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Publication details

The article was received on 08 Apr 2005, accepted on 24 Jun 2005 and first published on 22 Jul 2005


Article type: Communication
DOI: 10.1039/B504996B
Citation: Chem. Commun., 2005,0, 4211-4213
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    Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

    G. D. Jones, C. McFarland, T. J. Anderson and D. A. Vicic, Chem. Commun., 2005, 0, 4211
    DOI: 10.1039/B504996B

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