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Issue 27, 2005
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Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate

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Abstract

Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.

Graphical abstract: Synthesis of a four-coordinate titanium(iv) oxoanion via deprotonation and decarbonylation of complexed formate

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Publication details

The article was received on 31 Mar 2005, accepted on 16 May 2005 and first published on 09 Jun 2005


Article type: Communication
DOI: 10.1039/B504492H
Citation: Chem. Commun., 2005,0, 3403-3405
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    Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate

    A. Mendiratta, J. S. Figueroa and C. C. Cummins, Chem. Commun., 2005, 0, 3403
    DOI: 10.1039/B504492H

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