Issue 28, 2005
From the journal:

Chemical Communications

Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes†

John C. Stires, IV,a   Emily J. McLaurina  and  Clifford P. Kubiak*a  

* Corresponding authors

a University of California-San Diego, 9500 Gilman Drive, M.C. 0358, La Jolla, CA 92093-0358, USA
E-mail: ckubiak@ucsd.edu
Fax: +1 (858)534-5383
Tel: +1 (858)822-2477

Abstract

The position of the CN stretching frequency in infrared spectra of tetracyanoethylene (TCNE) complexed with methyl-substituted benzenes is used to determine the fraction of charge transferred from the electron donor to the acceptor.

Graphical abstract: Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes

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Article information

DOI
https://doi.org/10.1039/B504416B
Article type
Communication
Submitted
29 Mar 2005
Accepted
03 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3532-3534

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Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes

J. C. Stires, IV, E. J. McLaurin and C. P. Kubiak, Chem. Commun., 2005, 3532 DOI: 10.1039/B504416B

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