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Issue 24, 2005
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Dynamic kinetic resolution of N-Boc-2-lithiopyrrolidine

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Abstract

Asymmetric substitution of the organolithium derived either from N-Boc-2-tributylstannylpyrrolidine by tin–lithium exchange or from N-Boc-pyrrolidine by deprotonation occurs in the presence of a commercially available chiral diamine ligand with high levels of enantioselectivity by a dynamic kinetic resolution pathway.

Graphical abstract: Dynamic kinetic resolution of N-Boc-2-lithiopyrrolidine

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Publication details

The article was received on 21 Mar 2005, accepted on 22 Apr 2005 and first published on 11 May 2005


Article type: Communication
DOI: 10.1039/B504015A
Citation: Chem. Commun., 2005,0, 3083-3085
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    Dynamic kinetic resolution of N-Boc-2-lithiopyrrolidine

    I. Coldham, J. J. Patel and G. Sanchez-Jimenez, Chem. Commun., 2005, 0, 3083
    DOI: 10.1039/B504015A

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