Carbocycles with > 90% ee were prepared via Ir-catalysed asymmetric allylic alkylation/ring closing metathesis sequences or enantioselective Ir-catalysed intramolecular allylic alkylations.
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Carbocycles via enantioselective inter- and intramolecular iridium-catalysed allylic alkylations
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Organisch-Chemisches Institut der Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg, Germany
E-mail: g.helmchen@urz.uni-heidelberg.de ;
Fax: +49 6221 544205 ;
Tel: +49 6221 548401
E-mail: g.helmchen@urz.uni-heidelberg.de ;
Fax: +49 6221 544205 ;
Tel: +49 6221 548401
Chem. Commun., 2005, 2957-2959
DOI: 10.1039/B503713A
Received 14 Mar 2005, Accepted 14 Apr 2005
First published online 29 Apr 2005
Chemical Communications
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