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Issue 29, 2005
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Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Abstract

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)–salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

Graphical abstract: Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Publication details

The article was received on 14 Mar 2005, accepted on 13 May 2005 and first published on 10 Jun 2005


Article type: Communication
DOI: 10.1039/B503708E
Citation: Chem. Commun., 2005,0, 3661-3663
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    Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

    A. W. Kleij, M. Lutz, A. L. Spek, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2005, 0, 3661
    DOI: 10.1039/B503708E

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