Hindered rotation in an “exploded” biphenyl

Ognjen Š. Miljanić; Sangdon Han; Daniel Holmes; Gaston R. Schaller; K. Peter C. Vollhardt

doi:10.1039/B503173G

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Chemical Communications

Issue 20, 2005

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Hindered rotation in an “exploded” biphenyl

Ognjen Š. Miljanić , Sangdon Han , Daniel Holmes , Gaston R. Schaller and K. Peter C. Vollhardt

Chem. Commun., 2005, 2606-2608

DOI: 10.1039/B503173G
Received 03 Mar 2005, Accepted 21 Mar 2005
First published on the web 06 Apr 2005

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Abstract
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The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2′-bis(trimethylsilyl)-6,6′-bis(dimethylthexylsilyl)diphenylacetylene.

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Ognjen Š. Miljanić
Sangdon Han
Daniel Holmes
Gaston R. Schaller
K. Peter C. Vollhardt

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Chemical Communications

Hindered rotation in an “exploded” biphenyl

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