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Issue 29, 2005
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Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

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Abstract

The synthesis and flash column chromatographic separation of enantiomerically pure tris-adducts of C60 with an e,e,e-addition pattern is achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris(malonate) tethers.

Graphical abstract: Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

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Publication details

The article was received on 25 Feb 2005, accepted on 25 May 2005 and first published on 15 Jun 2005


Article type: Communication
DOI: 10.1039/B502822A
Citation: Chem. Commun., 2005,0, 3709-3711
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    Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

    N. Chronakis and A. Hirsch, Chem. Commun., 2005, 0, 3709
    DOI: 10.1039/B502822A

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