Issue 29, 2005

Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

Abstract

The synthesis and flash column chromatographic separation of enantiomerically pure tris-adducts of C60 with an e,e,e-addition pattern is achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris(malonate) tethers.

Graphical abstract: Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

Supplementary files

Article information

Article type
Communication
Submitted
25 Feb 2005
Accepted
25 May 2005
First published
15 Jun 2005

Chem. Commun., 2005, 3709-3711

Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

N. Chronakis and A. Hirsch, Chem. Commun., 2005, 3709 DOI: 10.1039/B502822A

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