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Issue 23, 2005
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Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

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Abstract

Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim]PF6, was highly efficient in the promotion of the Mizoroki–Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h−1), respectively.

Graphical abstract: Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

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Publication details

The article was received on 22 Feb 2005, accepted on 18 Apr 2005 and first published on 05 May 2005


Article type: Communication
DOI: 10.1039/B502528A
Citation: Chem. Commun., 2005,0, 2942-2944
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    Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

    H. Hagiwara, Y. Sugawara, T. Hoshi and T. Suzuki, Chem. Commun., 2005, 0, 2942
    DOI: 10.1039/B502528A

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