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Issue 21, 2005
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Tetraalkynyl calix[4]arenes with advanced NLO properties

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Abstract

Rigid, highly conjugated tetraalkynyl-calix[4]arenes synthesised via Sonogashira coupling give rise to improved second-order hyperpolarizability values as determined by hyper-Rayleigh scattering—a technique that in addition to X-ray crystallography also allows for the conformational analysis of the calixarene structures in solution.

Graphical abstract: Tetraalkynyl calix[4]arenes with advanced NLO properties

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Publication details

The article was received on 10 Feb 2005, accepted on 24 Mar 2005 and first published on 13 Apr 2005


Article type: Communication
DOI: 10.1039/B502045J
Citation: Chem. Commun., 2005, 2747-2749
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    Tetraalkynyl calix[4]arenes with advanced NLO properties

    G. Hennrich, M. T. Murillo, P. Prados, K. Song, I. Asselberghs, K. Clays, A. Persoons, J. Benet-Buchholz and J. de Mendoza, Chem. Commun., 2005, 2747
    DOI: 10.1039/B502045J

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