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Issue 18, 2005
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Cyclic dimer of a fused porphyrin zinc complex as a novel host with two π-electronically coupled binding sites

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Abstract

Upon complexation with 4,4′-bipyridine, a cyclic dimer of a fused porphyrin zinc complex, having two π-electronically coupled binding sites, shows a strong negative cooperativity in the second guest binding, to allow stepwise formation of 1 ∶ 1 and 1 ∶ 2 inclusion complexes.

Graphical abstract: Cyclic dimer of a fused porphyrin zinc complex as a novel host with two π-electronically coupled binding sites

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Publication details

The article was received on 03 Feb 2005, accepted on 04 Mar 2005 and first published on 15 Mar 2005


Article type: Communication
DOI: 10.1039/B501689D
Citation: Chem. Commun., 2005,0, 2324-2326
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    Cyclic dimer of a fused porphyrin zinc complex as a novel host with two π-electronically coupled binding sites

    H. Sato, K. Tashiro, H. Shinmori, A. Osuka and T. Aida, Chem. Commun., 2005, 0, 2324
    DOI: 10.1039/B501689D

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