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Issue 14, 2005
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Fourteen-vertex homo- and heterobimetallic metallacarboranes

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Abstract

Reduction of 4-(p-cymene)-4,1,12-closo-RuC2B10H12 followed by metallation with {M′} fragments (M′ = {CpCo2+}, {(arene)Ru2+} or {(dppe)Ni2+}) affords 14-vertex bimetallic 1,14,2,10-RuM′C2B10 species having bicapped hexagonal antiprismatic structures.

Graphical abstract: Fourteen-vertex homo- and heterobimetallic metallacarboranes

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Publication details

The article was received on 07 Jan 2005, accepted on 25 Jan 2005 and first published on 15 Feb 2005


Article type: Communication
DOI: 10.1039/B500236B
Citation: Chem. Commun., 2005,0, 1917-1919
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    Fourteen-vertex homo- and heterobimetallic metallacarboranes

    D. Ellis, M. E. Lopez, R. McIntosh, G. M. Rosair and A. J. Welch, Chem. Commun., 2005, 0, 1917
    DOI: 10.1039/B500236B

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