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Issue 15, 2005
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Synthesis of 4-substituted homoallylic alcohols via a one-pot tandem Lewis-acid catalyzed crotylboration-[3,3]-sigmatropic rearrangement

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Abstract

Crotylboration of aldehydes with E- or Z-crotylboronates in the presence of catalytic amounts of indium triflate provides the corresponding 4-substituted homoallylic alcohols.

Graphical abstract: Synthesis of 4-substituted homoallylic alcohols via a one-pot tandem Lewis-acid catalyzed crotylboration-[3,3]-sigmatropic rearrangement

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Publication details

The article was received on 20 Dec 2004, accepted on 03 Feb 2005 and first published on 18 Feb 2005


Article type: Communication
DOI: 10.1039/B418996E
Citation: Chem. Commun., 2005, 1988-1989
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    Synthesis of 4-substituted homoallylic alcohols via a one-pot tandem Lewis-acid catalyzed crotylboration-[3,3]-sigmatropic rearrangement

    P. V. Ramachandran, D. Pratihar and D. Biswas, Chem. Commun., 2005, 1988
    DOI: 10.1039/B418996E

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