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Issue 16, 2005
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Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts

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Abstract

Suzuki cross-coupling reactions are effected in both conventional organic solvents, under continuous flow conditions at 70 °C, and in batch mode in supercritical carbon dioxide (scCO2), at temperatures as low as 40 °C in the presence of palladium(II) acetate microencapsulated in polyurea [PdEnCat] and tetra-n-butylammonium salts.

Graphical abstract: Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (ii) acetate and tetra-n-butylammonium salts

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Publication details

The article was received on 14 Dec 2004, accepted on 04 Feb 2005 and first published on 09 Mar 2005


Article type: Communication
DOI: 10.1039/B418669A
Citation: Chem. Commun., 2005,0, 2175-2177
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    Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts

    C. K. Y. Lee, A. B. Holmes, S. V. Ley, I. F. McConvey, B. Al-Duri, G. A. Leeke, R. C. D. Santos and J. P. K. Seville, Chem. Commun., 2005, 0, 2175
    DOI: 10.1039/B418669A

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