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Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, 1 University Station, A5300, University of Texas at Austin, Austin, USA
E-mail: sessler@mail.utexas.edu
; Fax: +1 512 471 7550
; Tel: +1 512 471 5009
b
Universidad Autónoma de Madrid, Departmento de Química Orgánica, Campus de Cantoblanco, Madrid, Spain
E-mail: tomas.torres@uam.es
; Fax: +34 91 497 3966
; Tel: +34 91 497 4151
c
Universität Erlangen, Institute for Physical and Theoretical Chemistry, 91058 Erlangen, Germany
E-mail: dirk.guldi@chemie.uni-erlangen.de
; Fax: +49 9131 852 8307
; Tel: +49 9131 852 7341
Chem. Commun., 2005, 1892-1894
DOI:
10.1039/B418345B
Received
10 Dec 2004,
Accepted
26 Jan 2005
First published online
10 Feb 2005
A novel porphyrin–fullerene dyad assembled through Watson–Crick hydrogen bonds is described; this system undergoes photoinduced electron transfer upon irradiation with visible light to produce a charge separated state that is substantially longer lived than that of previous dyads of this type.
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