Issue 12, 2005

C–H Activation (γ-deprotonation) of a Sm(iii) bis(trimethylsilyl)amide complex via macrocyclic stabilisation of the sodium counter ion

Abstract

The γ-deprotonation of a samarium(III) bis(trimethylsilyl)amide complex derived from a dimetallated trans-dioxaporphyrinogen has been achieved through stabilisation of the counter cation within the macrocyclic cavity.

Graphical abstract: C–H Activation (γ-deprotonation) of a Sm(iii) bis(trimethylsilyl)amide complex via macrocyclic stabilisation of the sodium counter ion

Supplementary files

Article information

Article type
Communication
Submitted
24 Nov 2004
Accepted
06 Jan 2005
First published
27 Jan 2005

Chem. Commun., 2005, 1589-1591

C–H Activation (γ-deprotonation) of a Sm(III) bis(trimethylsilyl)amide complex via macrocyclic stabilisation of the sodium counter ion

J. Wang and M. G. Gardiner, Chem. Commun., 2005, 1589 DOI: 10.1039/B417679K

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