Issue 8, 2005
From the journal:

Chemical Communications

Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

Michelle Gilhespy,a   Martin Loka  and  Xavier Baucherel*a  

* Corresponding authors

a Johnson Matthey Catalysts, PO Box 1, Belasis Avenue, Billingham, Cleveland, UK
E-mail: xavier.baucherel@matthey.com

Abstract

PS-TEMPO, a polymer-supported 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)2 and Mn(NO3)2 as co-catalysts.

Graphical abstract: Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

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Article information

DOI
https://doi.org/10.1039/B415902K
Article type
Communication
Submitted
14 Oct 2004
Accepted
24 Nov 2004
First published
12 Jan 2005

Chem. Commun., 2005, 1085-1086

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Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

M. Gilhespy, M. Lok and X. Baucherel, Chem. Commun., 2005, 1085 DOI: 10.1039/B415902K

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