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Issue 1, 2005
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Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

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Abstract

The new compound [Ag2(bptz)3][AsF6]2, prepared from the reaction of bptz with Ag[AsF6] in CH3CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(I) ions with [AsF6] anions located in the folds of the cation.

Graphical abstract: Anion dependence of Ag(i) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

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Publication details

The article was received on 21 Jul 2004, accepted on 12 Oct 2004 and first published on 19 Nov 2004


Article type: Communication
DOI: 10.1039/B410811F
Citation: Chem. Commun., 2005, 46-47
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    Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

    B. L. Schottel, J. Bacsa and K. R. Dunbar, Chem. Commun., 2005, 46
    DOI: 10.1039/B410811F

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