Department of Chemistry and Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, USA
E-mail: firstname.lastname@example.org; Fax: +1 617 253 7929
; Tel: +1 617 253 4423
Chem. Commun., 2005, 23-36
04 Jun 2004,
17 Aug 2004
First published online
18 Oct 2004
Recent reports of highly conductive metallopolymers are reviewed. This literature is classified into one of two categories (inner or outer sphere) depending on the mode of interaction between the transition metal centers with each other and the conducting polymer backbone. The critical nature of charge transport is discussed in the context of the relative energies of the organic polymer-based and metal-centered redox processes. Also included are recent advances in the development of functional materials based on metal-containing conducting polymers.
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