Issue 33, 2005
From the journal:

Chemical Communications

Layer-by-layer assembly of charged poly(phenylacetylene)s with induced macromolecular helicity†

Katsuhiro Maeda,a   Yasuaki Matsushita,a   Muneyoshi Ezakaa  and  Eiji Yashima*ab  

* Corresponding authors

a Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan

b Yashima Super-structured Helix Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), Creation Core Nagoya 101, 2266-22 Anagahora, Shimoshidami, Moriyama-ku, Nagoya, Japan
E-mail: yashima@apchem.nagoya-u.ac.jp

Abstract

The macromolecular helicity of charged poly(phenylacetylene)s induced by small chiral guests in water can be retained by the alternative deposition of achiral polyelectrolytes with opposite charges, resulting in optically active multilayer thin films with a macromolecular helicity memory.

Graphical abstract: Layer-by-layer assembly of charged poly(phenylacetylene)s with induced macromolecular helicity

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Article information

DOI
https://doi.org/10.1039/B507863F
Article type
Communication
Submitted
03 Jun 2005
Accepted
04 Jul 2005
First published
26 Jul 2005

Chem. Commun., 2005, 4152-4154

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Layer-by-layer assembly of charged poly(phenylacetylene)s with induced macromolecular helicity

K. Maeda, Y. Matsushita, M. Ezaka and E. Yashima, Chem. Commun., 2005, 4152 DOI: 10.1039/B507863F

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