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Issue 7, 2005
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2-Arylallyl as a new protecting group for amines, amides and alcohols

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Abstract

Amines, amides and ethers containing 2-arylallyl groups are selectively and easily deprotected with tert-butyllithium. This transformation probably involves a carbolithiation reaction of the styrenyl moiety followed by a β-elimination process.

Graphical abstract: 2-Arylallyl as a new protecting group for amines, amides and alcohols

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Publication details

The article was received on 27 Sep 2004, accepted on 12 Nov 2004 and first published on 20 Dec 2004


Article type: Communication
DOI: 10.1039/B414966A
Citation: Chem. Commun., 2005,0, 933-935
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    2-Arylallyl as a new protecting group for amines, amides and alcohols

    J. Barluenga, F. J. Fañanás, R. Sanz, C. Marcos and J. M. Ignacio, Chem. Commun., 2005, 0, 933
    DOI: 10.1039/B414966A

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